The nation's sweetheart Kate Winslet made a dazzling first impression in a cobalt blue gown that hugged her every curve and showed off her toned arms in an intricate halterneck neckline.
A daring thigh slit showed off a subtle hint of the 40-year-old's toned pins, whilst she styled her hair in a chic side swept up-do, giving a nod to the twenties style.
And attending the event dressed for success seemed to do wonders for the star, as she walked away with the Golden Globe award for Best Actress in a Supporting Role for her work in the Steve Jobs biopic.
Meanwhile, Rosie Huntington-Whiteley was every bit the golden girl as she walked the red carpet in a figure hugging gold Versace Atelier gown. It was a special night for her as she announced her engagement to Jason Statham following a five year relationship.
She flashed her diamond ring as she posed for pictures, with reps confirming to MailOnline that she and her action man beau are set to marry.
Explaining her reason behind choosing the dress, she joked: 'I love gold.'
Game Of Thrones actress Emilia Clarke also dazzled in a sheer lace black gown for the evening, exposing her toned arms under the unique cape-style sleeves.
And proving that sometimes it pays to break the fashion rules, Natalie dazzled in a crimson off the shoulder dress that clashed with the red carpet but made her look breathtaking.